Database : MEDLINE
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[PMID]: 29521567
[Au] Autor:Fasano E; Arnese A; Esposito F; Albano L; Masucci A; Capelli C; Cirillo T; Nardone A
[Ad] Address:a Department of Agricultural Sciences , University of Naples Federico II , Portici , Naples , Italy.
[Ti] Title:Evaluation of the impact of anthropogenic activities on arsenic, cadmium, chromium, mercury, lead, and polycyclic aromatic hydrocarbon levels in seafood from the Gulf of Naples, Italy.
[So] Source:J Environ Sci Health A Tox Hazard Subst Environ Eng;:1-7, 2018 Mar 09.
[Is] ISSN:1532-4117
[Cp] Country of publication:England
[La] Language:eng
[Ab] Abstract:The principal aim of this study was to monitor the occurrence of some metals and polycyclic aromatic hydrocarbons (PAHs) in fish and mussels from the Gulf of Naples. A comparison with previous researches of the same area was carried out, and the intakes of these compounds through the diet and their effect on the tolerable intake values (when available) were assessed. Cadmium (Cd), chromium (Cr), and lead (Pb) were detected by flameless atomic absorption spectroscopy (Cd, Cr, and Pb); arsenic (As) and mercury (Hg) were detected by applying the hydride method. PAHs were detected by high-performance liquid chromatography. Widespread contamination was found. Among the metals, Hg showed the highest maximum levels of 284.94 ng/g wet weight (ww) in fish and 480.00 ng/g ww in mussels. Chrysene, phenanthrene, fluoranthene, anthracene, and benzo[k]fluoranthene were the most common PAHs in fish, whereas benzo[a]anthracene, pyrene, phenanthrene, acenaphthylene, and acenaphthene were the most frequently occurring compounds in mussels. The concentrations of As, Cr, Hg, Pb, and PAHs in fish were found to decrease over a period of 30 years, whereas the Cd levels remained constant. The Hg, Pb, and PAH levels in mussels increased over the period 2010 to 2016. Finally, the average consumption of mussels led to the highest effect on the Tolerable Daily Intake of Hg, which was exceeded by 19%.
[Pt] Publication type:JOURNAL ARTICLE
[Em] Entry month:1803
[Cu] Class update date: 180309
[Lr] Last revision date:180309
[St] Status:Publisher
[do] DOI:10.1080/10934529.2018.1445075

  2 / 17791 MEDLINE  
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[PMID]: 29385474
[Au] Autor:Seibert JT; Abuajamieh M; Sanz Fernandez MV; Johnson JS; Kvidera SK; Horst EA; Mayorga EJ; Lei S; Patience JF; Ross JW; Rhoads RP; Johnson RC; Lonergan SM; Perfield JW; Baumgard LH
[Ad] Address:Department of Animal Science, Iowa State University, Ames, IA.
[Ti] Title:Effects of heat stress and insulin sensitizers on pig adipose tissue.
[So] Source:J Anim Sci;96(2):510-520, 2018 Mar 06.
[Is] ISSN:1525-3163
[Cp] Country of publication:United States
[La] Language:eng
[Ab] Abstract:Heat stress (HS) negatively impacts several swine production variables, including carcass fat quality and quantity. Pigs reared in HS have more adipose tissue than energetically predicted, explainable, in part, by HS-induced hyperinsulinemia. Study objectives were to evaluate insulin's role in altering fat characteristics during HS via feeding insulin-sensitizing compounds. Forty crossbred barrows (113 ± 9 kg BW) were randomly assigned to one of five environment by diet treatments: 1) thermoneutral (TN) fed ad libitum (TNAL), 2) TN and pair-fed (TNPF), 3) HS fed ad libitum (HSAL), 4) HS fed ad libitum with sterculic oil (SO) supplementation (HSSO; 13 g/d), and 5) HS fed ad libitum with dietary chromium (Cr) supplementation (HSCr; 0.5 mg/d; Kemin Industries, Des Moines, IA). The study consisted of three experimental periods (P). During P0 (2 d), all pigs were exposed to TN conditions (23 ± 3 °C, 68 ± 10% RH) and fed ad libitum. During P1 (7 d), all pigs received their respective dietary supplements, were maintained in TN conditions, and fed ad libitum. During P2 (21 d), HSAL, HSSO, and HSCr pigs were fed ad libitum and exposed to cyclical HS conditions (28 to 33 °C, 58 ± 10% RH). The TNAL and TNPF pigs remained in TN conditions and were fed ad libitum or pair-fed to their HSAL counterparts. Rectal temperature (TR), respiration rate (RR), and skin temperature (TS) were obtained daily at 0600 and 1800 h. At 1800 h, HS exposed pigs had increased TR, RR, and TS relative to TNAL controls (1.13 °C, 48 bpm, and 3.51 °C, respectively; P < 0.01). During wk 2 and 3 of P2, HSSO pigs had increased 1800 h TR relative to HSAL and HSCr (~0.40 and ~0.42 °C, respectively; P ≤ 0.05). Heat stress decreased ADFI and ADG compared to TNAL pigs (2.24 vs. 3.28 and 0.63 vs. 1.09 kg/d, respectively; P < 0.01) and neither variable was affected by SO or Cr supplementation. Heat stress increased or tended to increase moisture content of abdominal (7.7 vs. 5.9%; P = 0.07) and inner s.c. (11.4 vs. 9.8%; P < 0.05) adipose depots compared to TNAL controls. Interestingly, TNPF pigs also had increased adipose tissue moisture content and this was most pronounced in the outer s.c. depot (15.0 vs. 12.2%; P < 0.01) compared to TNAL pigs. Heat stress had little or no effect on fatty acid composition of abdominal, inner, and outer s.c. adipose tissue depots. In summary, the negative effects of HS on fat quality do not appear to be fatty acid composition related, but may be explained by increased adipose tissue moisture content.
[Pt] Publication type:JOURNAL ARTICLE
[Em] Entry month:1802
[Cu] Class update date: 180308
[Lr] Last revision date:180308
[St] Status:In-Process
[do] DOI:10.1093/jas/skx067

  3 / 17791 MEDLINE  
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[PMID]: 29508017
[Au] Autor:Arcega-Cabrera F; Fargher L; Quesadas-Rojas M; Moo-Puc R; Oceguera-Vargas I; Noreña-Barroso E; Yáñez-Estrada L; Alvarado J; González L; Pérez-Herrera N; Pérez-Medina S
[Ad] Address:Unidad de Química Sisal, Facultad de Química, Universidad Nacional Autónoma de México, Puerto de Abrigo Sisal, 97355, Yucatán, Mexico. farcega@unam.mx.
[Ti] Title:Environmental Exposure of Children to Toxic Trace Elements (Hg, Cr, As) in an Urban Area of Yucatan, Mexico: Water, Blood, and Urine Levels.
[So] Source:Bull Environ Contam Toxicol;, 2018 Mar 05.
[Is] ISSN:1432-0800
[Cp] Country of publication:United States
[La] Language:eng
[Ab] Abstract:Merida is the largest urban center in the Mexican State of Yucatan. Here domestic sewage is deposited in poorly built septic tanks and is not adequately treated. Because of contamination from such waste, water from the top 20 m of the aquifer is unsuitable for human consumption. Given this situation and because children are highly vulnerable to environmental pollution, including exposure to toxic trace elements, this study focused on evaluating the exposure of children to arsenic (As), chromium (Cr), and mercury (Hg) in water. It also evaluated the relationship between the levels of these elements in water and their concentrations in urine and blood. Among the 33 children monitored in the study, arsenic surpassed WHO limits for blood in 37% of the cases, which could result from the ingestion of poultry contaminated with organoarsenic compounds. In the case of WHO limits for Mercury, 65% of the water samples analyzed, 28% of urine samples, and 12% of blood samples exceeded them. Mercury exposure was correlated with biological sex, some lifestyle factors, and the zone in Merida in which children live. These data suggest that the levels of some toxic metals in children may be affected by water source, socioeconomic factors, and individual behavior.
[Pt] Publication type:JOURNAL ARTICLE
[Em] Entry month:1803
[Cu] Class update date: 180306
[Lr] Last revision date:180306
[St] Status:Publisher
[do] DOI:10.1007/s00128-018-2306-8

  4 / 17791 MEDLINE  
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[PMID]: 29412641
[Au] Autor:Robledo JI; Leani JJ; Karydas AG; Migliori A; Pérez CA; Sánchez HJ
[Ad] Address:IFEG , National Scientific and Technical Research Council (CONICET) , X5000HUA - Córdoba , Argentina.
[Ti] Title:Energy-Dispersive Total-Reflection Resonant Inelastic X-ray Scattering as a Tool for Elemental Speciation in Contaminated Water.
[So] Source:Anal Chem;, 2018 Mar 06.
[Is] ISSN:1520-6882
[Cp] Country of publication:United States
[La] Language:eng
[Ab] Abstract:This work presents a state-of the-art analytical methodology, by which chemical state information on metallic elements is obtained for liquid samples in a fast and simple manner. This method overcomes limitations of conventional X-ray techniques, such as X-ray absorption spectroscopy, by applying resonant inelastic X-ray scattering under total reflection geometry (TRIXS). TRIXS is particularly applicable for the analysis of small quantity of liquid samples deposited on polished reflectors. This feature is relevant for the chemical speciation of metallic trace elements contained in water samples, since the degree of their toxicity depends crucially on the concentration of specific chemical species included. The analytical merits of the proposed methodology were studied at Elettra Sincrotrone Trieste and at the Brazilian Synchrotron Light Laboratory. Contaminated water samples with low concentration of different chromium and manganese compounds were measured. Results prove the analytical potential of the TRIXS technique in characterizing different chemical species of metallic elements in water samples.
[Pt] Publication type:JOURNAL ARTICLE
[Em] Entry month:1802
[Cu] Class update date: 180306
[Lr] Last revision date:180306
[St] Status:Publisher
[do] DOI:10.1021/acs.analchem.7b04624

  5 / 17791 MEDLINE  
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[PMID]: 29492714
[Au] Autor:Salcedo R; Bosquez M
[Ad] Address:Instituto de Investigaciones en Materiales, Universidad Nacional Autónoma de México, circuito exterior s/n. Ciudad universitaria, 04510, Coyoacan, Ciudad de México, Mexico. salcevitch@gmail.com.
[Ti] Title:Schiff base complexes that form sandwich compounds.
[So] Source:J Mol Model;24(3):72, 2018 Feb 28.
[Is] ISSN:0948-5023
[Cp] Country of publication:Germany
[La] Language:eng
[Ab] Abstract:In this article, we explore the capacity of formed Schiff base complexes to trap metal atoms or ions, using their aromatic ends. The intrinsic geometry of each complex defines the process of substitution. Two cases were studied; one involving a trans Schiff base complex and the other considering how a salen ligand, with nickel systems traps chromium. We also assessed the nature of the new bonds and the frontier molecular orbitals. Graphical abstract Two salen nickel compounds are joint by a Cr(0) atom forming an organometallic interaction.
[Pt] Publication type:JOURNAL ARTICLE
[Em] Entry month:1803
[Cu] Class update date: 180305
[Lr] Last revision date:180305
[St] Status:In-Process
[do] DOI:10.1007/s00894-018-3607-x

  6 / 17791 MEDLINE  
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[PMID]: 29431434
[Au] Autor:Lemoine P; Vernière A; Pasturel M; Venturini G; Malaman B
[Ad] Address:Univ. Rennes, CNRS , ISCR-UMR 6226 , F-35000 Rennes , France.
[Ti] Title:Unexpected Magnetic Ordering on the Cr Substructure in UCr Si C and Structural Relationships in Quaternary U-Cr-Si-C Compounds.
[So] Source:Inorg Chem;57(5):2546-2557, 2018 Mar 05.
[Is] ISSN:1520-510X
[Cp] Country of publication:United States
[La] Language:eng
[Ab] Abstract:Previous experimental and theoretical studies revealed that carbon insertion into the RCr Si compounds drastically affects the magnetic behavior, since chromium does not carry any magnetic moment in RCr Si C (R = Y, La-Sm, Gd-Er) compounds in contrast to RCr Si (R = Y, Sm, Gd-Lu, Th) compounds. In this study, we report on the unexpected magnetic ordering of chromium atoms in the isotype quaternary UCr Si C compound. While specific heat and magnetic measurements suggest a Pauli paramagnetic behavior, neutron powder diffraction reveals an antiferromagnetic ordering of the chromium substructure at high temperature ( T > 300 K), while that of uranium remains nonmagnetically ordered down to 2 K. Its magnetic behavior, inverse in comparison to the RCr Si C carbides involving a magnetic lanthanide, is discussed in relation with the singularity of its crystal structure among the series. Moreover, the crystallographic structures and the structural stability of UCr Si C and of two other quaternary U-Cr-Si-C compounds (i.e., UCr Si C and U Cr Si C ), based on the full occupancy of interstitial sites by carbon atoms, are discussed and compared to those of the related ternary intermetallics. Finally, the low-temperature form of UCr Si , corresponding to a displacive transformation around 210 K of the ThCr Si -type structure, is reinvestigated by considering a higher symmetry monoclinic unit cell ( C2/ m) instead of the previously reported triclinic cell ( P1Ì…). The antiferromagnetic ordering at low temperature ( T = 30(2) K) of the uranium substructure is confirmed, and its magnetic structure is reanalyzed and discussed considering the monoclinic crystal structure.
[Pt] Publication type:JOURNAL ARTICLE
[Em] Entry month:1802
[Cu] Class update date: 180305
[Lr] Last revision date:180305
[St] Status:In-Process
[do] DOI:10.1021/acs.inorgchem.7b02901

  7 / 17791 MEDLINE  
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[PMID]: 29424996
[Au] Autor:Filatova OV; Kovrigin AO; Voronina IY; Pavlova IP; Balanova AV
[Ti] Title:[Features of physical development of girls residing in the altai territory with the different level of the environmental load].
[So] Source:Gig Sanit;95(7):643-8, 2016.
[Is] ISSN:0016-9900
[Cp] Country of publication:Russia (Federation)
[La] Language:rus
[Ab] Abstract:There was performed the determination of the characteristics of the physical development of 660 girls aged of from 6 years 6 months to 17years 5 months 29 days, residing in the Blagoveshchenskiy and the Ust-Pristanskiy regions of the Altai Krai. The Blagoveshchenskiy region is characterized by a high level of ambient air pollution (potential of the atmospheric pollution accounts for 2.7-3.0). Sodium sulfate, sulfur dioxide, hydrogen sulfide, carbonic oxide, nitrogen dioxide, vanadium pentoxide, ammonia, manganese and its compounds, hexavalent chromium make the greatest contribution to the atmospheric pollution. The Ust-Pristanskiy region is referred to the least polluted territories of the Altai Krai. Living conditions in the Blagoveshchenskiy region of the Altai Krai were found to influence on the girls ' physical and sexual development. The girls living in the Blagoveshchenskiy region show the pubertal growth spurt one year later, which is lasting longer. As a result, by the age of 17, measurements of the body and leg length are almost 6 cm higher in girls of the Blagoveshchenskiy region. 97% of the Blagoveshchenskiy region residents have pathological (trochanter index ≤ 1.85) and disevolutive (trochanter index = 1.86 - 1.91) types of age evolution which testifies to the thyroid and reproductive hormones deficiency. Among the residents of the Ust-Pristanskiy region, 80% have either normal values of the trochanter index (1.95 - 2.0) or slightly deviated from the norm (hypoevolutive, normoevolutive, and hyperevolutive types of age evolution). The level of the endocrine system diseases prevalence, nutrition and metabolic disorders among the teenagers of the Blagoveshchenskiy region are 2.5 times higher than in the rural area of the Altai Krai. The relative risk of the endocrine system diseases occurrence, nutrition disturbances and metabolic disorders in the teenagers of the Blagoveshchenskiy region equals to OR=1.87 (x=272.7, p<0.001).
[Mh] MeSH terms primary: Adolescent Development/physiology
Child Development/physiology
Environmental Exposure
Environmental Illness
[Mh] MeSH terms secundary: Adolescent
Child
Environmental Exposure/analysis
Environmental Exposure/prevention & control
Environmental Exposure/statistics & numerical data
Environmental Illness/epidemiology
Environmental Illness/prevention & control
Environmental Monitoring/methods
Environmental Monitoring/statistics & numerical data
Female
Humans
Prevalence
Siberia/epidemiology
[Pt] Publication type:JOURNAL ARTICLE
[Em] Entry month:1803
[Cu] Class update date: 180301
[Lr] Last revision date:180301
[Js] Journal subset:IM
[Da] Date of entry for processing:180210
[St] Status:MEDLINE

  8 / 17791 MEDLINE  
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[PMID]: 29424495
[Au] Autor:Bekmuhambetov EZ; Mamyrbaev AA; Dzharkenov TA
[Ti] Title:[Hygienic assessment of working conditions in the production of ferro-alloys].
[So] Source:Gig Sanit;95(6):545-8, 2016.
[Is] ISSN:0016-9900
[Cp] Country of publication:Russia (Federation)
[La] Language:rus
[Ab] Abstract:This work is devoted to the study of conditions of the work of employees of the modern ferro-alloy production, which was performed in the framework of the evaluation of working places at the Open Joint-Stock Company «Ferrokhrom¼, which is part of Joint-Stock Transnational Company "Kazchrom". The studies were performed with account of the full range of the list of working places, both in the main and auxiliary shops. The work activity of the workers from leading professional groups was established to be conjugate of the impact of the complex of unfavorable factors of occupational environment and labor process. There are given comprehensive measures to improve working conditions and health maintenance in workers from leading professional groups.
[Mh] MeSH terms primary: Chromium Alloys
Ferrous Compounds
Metallurgy
Occupational Diseases
Public Health/methods
Workplace
[Mh] MeSH terms secundary: Health Status Indicators
Humans
Kazakhstan/epidemiology
Metallurgy/methods
Metallurgy/organization & administration
Metallurgy/standards
Occupational Diseases/epidemiology
Occupational Diseases/etiology
Occupational Diseases/prevention & control
Occupational Exposure/adverse effects
Occupational Exposure/prevention & control
Occupational Exposure/statistics & numerical data
Population Health/statistics & numerical data
Risk Assessment
Workplace/standards
Workplace/statistics & numerical data
[Pt] Publication type:JOURNAL ARTICLE
[Nm] Name of substance:0 (Chromium Alloys); 0 (Ferrous Compounds)
[Em] Entry month:1803
[Cu] Class update date: 180301
[Lr] Last revision date:180301
[Js] Journal subset:IM
[Da] Date of entry for processing:180210
[St] Status:MEDLINE

  9 / 17791 MEDLINE  
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[PMID]: 29424217
[Au] Autor:Zhurba OM; Rukavishnikov VS; Merinov AV; Alekseyenko AN
[Ti] Title:[The content of petroleum products, benzo(a)pyrene and heavy metals in soils of yamalnenets autonomous district and heavy metals in the hair of children].
[So] Source:Gig Sanit;95(6):521-4, 2016.
[Is] ISSN:0016-9900
[Cp] Country of publication:Russia (Federation)
[La] Language:rus
[Ab] Abstract:The paper presents information about the content of benzo(a)pyrene in soil samples of petroleum products and the content of heavy metals (iron, copper, lead, arsenic, manganese, chromium, cadmium and mercury) in the soil and hair samples of children. Soil samples and hair were taken in October 2014 in the north-western part of the Yamal-Nenets Autonomous District. The values obtained were compared with the approximately permissible levels and maximum allowable concentrations adopted in the Russian Federation. Levels are determined compounds in the soil in general do not exceed the allowable concentrations. In hair samples there was noted marked exceeding of the recommended values for zinc, copper, chromium and iron 10%, 16.7%, 83.3% and 100% samples, respectively. The cause of the high iron content in the hair samples may be due to the quality of consumed water, which is characterized by low mineralization and high iron content. Increased chromium content of more than 80% of the hair samples can be caused, as in the case of iron, the quality of water consumed, but also a high proportion of local foods in the diet of people, rich by chromium. A conducted study on the state of the environment in the village, away from areas of hydrocarbon production, indicates to the low importance of anthropogenic impact.
[Mh] MeSH terms primary: Hair/chemistry
Metals, Heavy
Soil Pollutants
Water Pollutants, Chemical
[Mh] MeSH terms secundary: Arctic Regions/epidemiology
Benzo(a)pyrene/analysis
Child
Ecological Parameter Monitoring/methods
Ecological Parameter Monitoring/standards
Environmental Monitoring/methods
Environmental Monitoring/standards
Female
Humans
Male
Metals, Heavy/analysis
Metals, Heavy/classification
Petroleum/analysis
Risk Assessment/methods
Risk Assessment/statistics & numerical data
Russia/epidemiology
Soil Pollutants/analysis
Soil Pollutants/standards
Water Pollutants, Chemical/analysis
Water Pollutants, Chemical/standards
[Pt] Publication type:JOURNAL ARTICLE
[Nm] Name of substance:0 (Metals, Heavy); 0 (Petroleum); 0 (Soil Pollutants); 0 (Water Pollutants, Chemical); 3417WMA06D (Benzo(a)pyrene)
[Em] Entry month:1803
[Cu] Class update date: 180301
[Lr] Last revision date:180301
[Js] Journal subset:IM
[Da] Date of entry for processing:180210
[St] Status:MEDLINE

  10 / 17791 MEDLINE  
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[PMID]: 29343827
[Au] Autor:Page BDG; Valerie NCK; Wright RHG; Wallner O; Isaksson R; Carter M; Rudd SG; Loseva O; Jemth AS; Almlöf I; Font-Mateu J; Llona-Minguez S; Baranczewski P; Jeppsson F; Homan E; Almqvist H; Axelsson H; Regmi S; Gustavsson AL; Lundbäck T; Scobie M; Strömberg K; Stenmark P; Beato M; Helleday T
[Ad] Address:Science for Life Laboratory, Division of Translational Medicine and Chemical Biology, Department of Medical Biochemistry and Biophysics, Karolinska Institutet, Solna, SE-171 21, Sweden. brent.page@scilifelab.se.
[Ti] Title:Targeted NUDT5 inhibitors block hormone signaling in breast cancer cells.
[So] Source:Nat Commun;9(1):250, 2018 01 17.
[Is] ISSN:2041-1723
[Cp] Country of publication:England
[La] Language:eng
[Ab] Abstract:With a diverse network of substrates, NUDIX hydrolases have emerged as a key family of nucleotide-metabolizing enzymes. NUDT5 (also called NUDIX5) has been implicated in ADP-ribose and 8-oxo-guanine metabolism and was recently identified as a rheostat of hormone-dependent gene regulation and proliferation in breast cancer cells. Here, we further elucidate the physiological relevance of known NUDT5 substrates and underscore the biological requirement for NUDT5 in gene regulation and proliferation of breast cancer cells. We confirm the involvement of NUDT5 in ADP-ribose metabolism and dissociate a relationship to oxidized nucleotide sanitation. Furthermore, we identify potent NUDT5 inhibitors, which are optimized to promote maximal NUDT5 cellular target engagement by CETSA. Lead compound, TH5427, blocks progestin-dependent, PAR-derived nuclear ATP synthesis and subsequent chromatin remodeling, gene regulation and proliferation in breast cancer cells. We herein present TH5427 as a promising, targeted inhibitor that can be used to further study NUDT5 activity and ADP-ribose metabolism.
[Mh] MeSH terms primary: Enzyme Inhibitors/pharmacology
Progestins/metabolism
Pyrophosphatases/antagonists & inhibitors
Signal Transduction/drug effects
[Mh] MeSH terms secundary: Adenosine Diphosphate Ribose/metabolism
Adenosine Triphosphate/metabolism
Breast Neoplasms/genetics
Breast Neoplasms/metabolism
Breast Neoplasms/pathology
Cell Line, Tumor
Cell Nucleus/drug effects
Cell Nucleus/metabolism
Cell Proliferation/drug effects
Cell Proliferation/genetics
Enzyme Inhibitors/chemistry
Enzyme Inhibitors/metabolism
Female
HL-60 Cells
Humans
Molecular Structure
Pyrophosphatases/genetics
Pyrophosphatases/metabolism
RNA Interference
Substrate Specificity
[Pt] Publication type:JOURNAL ARTICLE; RESEARCH SUPPORT, NON-U.S. GOV'T
[Nm] Name of substance:0 (Enzyme Inhibitors); 0 (Progestins); 20762-30-5 (Adenosine Diphosphate Ribose); 8L70Q75FXE (Adenosine Triphosphate); EC 3.6.1.- (NUDT5 protein, human); EC 3.6.1.- (Pyrophosphatases)
[Em] Entry month:1802
[Cu] Class update date: 180227
[Lr] Last revision date:180227
[Js] Journal subset:IM
[Da] Date of entry for processing:180119
[St] Status:MEDLINE
[do] DOI:10.1038/s41467-017-02293-7


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