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[PMID]:28117750
[Au] Autor:Liu H; Bian J; Wang Z; Hou CJ
[Ad] Endereço:Key Laboratory of Materials Modification by Laser, Ion and Electron Beams (Ministry of Education), School of Physics and Optoelectronic Technology, Dalian University of Technology, Dalian 116024, China. liuhz418@163.com.
[Ti] Título:Synthesis and Characterization of Waterborne Fluoropolymers Prepared by the One-Step Semi-Continuous Emulsion Polymerization of Chlorotrifluoroethylene, Vinyl Acetate, Butyl Acrylate, Veova 10 and Acrylic Acid.
[So] Source:Molecules;22(1), 2017 Jan 22.
[Is] ISSN:1420-3049
[Cp] País de publicação:Switzerland
[La] Idioma:eng
[Ab] Resumo:Waterborne fluoropolymer emulsions were synthesized using the one-step semi-continuous seed emulsion polymerization of chlorotrifluoroethylene (CTFE), vinyl acetate (VAc), -butyl acrylate (BA), Veova 10, and acrylic acid (AA). The main physical parameters of the polymer emulsions were tested and analyzed. Characteristics of the polymer films such as thermal stability, glass transition temperature, film-forming properties, and IR spectrum were studied. Meanwhile, the weatherability of fluoride coatings formulated by the waterborne fluoropolymer and other coatings were evaluated by the quick ultraviolet (QUV) accelerated weathering test, and the results showed that the fluoropolymer with more than 12% fluoride content possessed outstanding weather resistance. Moreover, scale-up and industrial-scale experiments of waterborne fluoropolymer emulsions were also performed and investigated.
[Mh] Termos MeSH primário: Acrilatos/química
Clorofluorcarbonetos/química
Ácidos Decanoicos/química
Polímeros de Fluorcarboneto/síntese química
Compostos de Vinila/química
[Mh] Termos MeSH secundário: Calorimetria
Emulsões/química
Polimerização
Espectroscopia de Infravermelho com Transformada de Fourier
Tempo (Meteorologia)
[Pt] Tipo de publicação:JOURNAL ARTICLE
[Nm] Nome de substância:
0 (Acrylates); 0 (Chlorofluorocarbons); 0 (Decanoic Acids); 0 (Emulsions); 0 (Fluorocarbon Polymers); 0 (Vinyl Compounds); 705NM8U35V (n-butyl acrylate); AF215GW34G (chlorotrifluoroethylene); J94PBK7X8S (acrylic acid); L9MK238N77 (vinyl acetate)
[Em] Mês de entrada:1705
[Cu] Atualização por classe:170523
[Lr] Data última revisão:
170523
[Sb] Subgrupo de revista:IM
[Da] Data de entrada para processamento:170125
[St] Status:MEDLINE


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[PMID]:27976587
[Au] Autor:Martin ET; McGuire CM; Mubarak MS; Peters DG
[Ad] Endereço:Department of Chemistry, Indiana University , Bloomington, Indiana 47405, United States.
[Ti] Título:Electroreductive Remediation of Halogenated Environmental Pollutants.
[So] Source:Chem Rev;116(24):15198-15234, 2016 Dec 28.
[Is] ISSN:1520-6890
[Cp] País de publicação:United States
[La] Idioma:eng
[Ab] Resumo:Electrochemical reduction of halogenated organic compounds is gaining increasing attention as a strategy for the remediation of environmental pollutants. We begin this review by discussing key components (cells, electrodes, solvents, and electrolytes) in the design of a procedure for degrading a targeted pollutant, and we describe and contrast some experimental techniques used to explore and characterize the electrochemical behavior of that pollutant. Then, we describe how to probe various mechanistic features of the pertinent electrochemistry (including stepwise versus concerted carbon-halogen bond cleavage, identification of reaction intermediates, and elucidation of mechanisms). Knowing this information is vital to the successful development of a remediation procedure. Next, we outline techniques, instrumentation, and cell designs involved in scaling up a benchtop experiment to an industrial-scale system. Finally, the last and major part of this review is directed toward surveying electrochemical studies of various categories of halogenated pollutants (chlorofluorocarbons; disinfection byproducts; pesticides, fungicides, and bactericides; and flame retardants) and looking forward to future developments.
[Mh] Termos MeSH primário: Poluentes Ambientais/química
Hidrocarbonetos Clorados/química
Gerenciamento de Resíduos/métodos
[Mh] Termos MeSH secundário: Antibacterianos/química
Antifúngicos/química
Clorofluorcarbonetos/química
Complexos de Coordenação/química
Desinfetantes/química
Técnicas Eletroquímicas
Retardadores de Chama
Oxirredução
Praguicidas/química
[Pt] Tipo de publicação:JOURNAL ARTICLE; REVIEW
[Nm] Nome de substância:
0 (Anti-Bacterial Agents); 0 (Antifungal Agents); 0 (Chlorofluorocarbons); 0 (Coordination Complexes); 0 (Disinfectants); 0 (Environmental Pollutants); 0 (Flame Retardants); 0 (Hydrocarbons, Chlorinated); 0 (Pesticides)
[Em] Mês de entrada:1709
[Cu] Atualização por classe:170926
[Lr] Data última revisão:
170926
[Sb] Subgrupo de revista:IM
[Da] Data de entrada para processamento:161216
[St] Status:MEDLINE
[do] DOI:10.1021/acs.chemrev.6b00531


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[PMID]:27974774
[Au] Autor:Molina M; Janda K
[Ti] Título:Ralph J. Cicerone (1943-2016).
[So] Source:Nature;540(7633):342, 2016 12 14.
[Is] ISSN:1476-4687
[Cp] País de publicação:England
[La] Idioma:eng
[Mh] Termos MeSH primário: Mudança Climática
Política Ambiental/história
[Mh] Termos MeSH secundário: Animais
Clorofluorcarbonetos/história
Edição de Genes/história
Golfo do México
História do Século XX
História do Século XXI
Seres Humanos
National Academy of Sciences (U.S.)/organização & administração
Ozônio/história
Poluição por Petróleo/efeitos adversos
Estados Unidos
[Pt] Tipo de publicação:BIOGRAPHY; HISTORICAL ARTICLE; JOURNAL ARTICLE; PORTRAITS
[Ps] Nome de pessoa como assunto:Cicerone RJ
[Nm] Nome de substância:
0 (Chlorofluorocarbons); 66H7ZZK23N (Ozone)
[Em] Mês de entrada:1704
[Cu] Atualização por classe:170407
[Lr] Data última revisão:
170407
[Sb] Subgrupo de revista:IM
[Da] Data de entrada para processamento:161216
[St] Status:MEDLINE
[do] DOI:10.1038/540342a


  4 / 580 MEDLINE  
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[PMID]:27905700
[Au] Autor:Food and Drug Administration, HHS
[Ti] Título:Use of Ozone-Depleting Substances. Direct final rule.
[So] Source:Fed Regist;81(207):74298-302, 2016 Oct 26.
[Is] ISSN:0097-6326
[Cp] País de publicação:United States
[La] Idioma:eng
[Ab] Resumo:The Food and Drug Administration (FDA, the Agency, or we) is amending its regulation on uses of ozone-depleting substances (ODSs), including chlorofluorocarbons (CFCs), to remove the designation for certain products as "essential uses" under the Clean Air Act. Essential-use products are exempt from the ban by FDA on the use of CFCs and other ODS propellants in FDA-regulated products and from the ban by the Environmental Protection Agency (EPA) on the use of ODSs in pressurized dispensers. The products that will no longer constitute an essential use are: Sterile aerosol talc administered intrapleurally by thoracoscopy for human use and metered-dose atropine sulfate aerosol human drugs administered by oral inhalation. FDA is taking this action because alternative products that do not use ODSs are now available and because these products are no longer being marketed in versions that contain ODSs.
[Mh] Termos MeSH primário: Propelentes de Aerossol/efeitos adversos
Poluentes Atmosféricos/efeitos adversos
Clorofluorcarbonetos/efeitos adversos
Perda de Ozônio/legislação & jurisprudência
United States Food and Drug Administration/legislação & jurisprudência
[Mh] Termos MeSH secundário: Propelentes de Aerossol/uso terapêutico
Atropina/uso terapêutico
Clorofluorcarbonetos/uso terapêutico
Seres Humanos
Perda de Ozônio/prevenção & controle
Talco/uso terapêutico
Estados Unidos
[Pt] Tipo de publicação:JOURNAL ARTICLE
[Nm] Nome de substância:
0 (Aerosol Propellants); 0 (Air Pollutants); 0 (Chlorofluorocarbons); 14807-96-6 (Talc); 7C0697DR9I (Atropine)
[Em] Mês de entrada:1612
[Cu] Atualização por classe:161217
[Lr] Data última revisão:
161217
[Sb] Subgrupo de revista:T
[Da] Data de entrada para processamento:161203
[St] Status:MEDLINE


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[PMID]:27372116
[Au] Autor:Zheng L; Wu Z; Zhang Y; Wei Y; Wang J
[Ad] Endereço:Key Laboratory of Drinking Water Science and Technology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China; Beijing Key Laboratory of Industrial Wastewater Treatment and Resource Recovery, Research Center for Eco-Environmental Sciences, Chinese Academ
[Ti] Título:Effect of non-solvent additives on the morphology, pore structure, and direct contact membrane distillation performance of PVDF-CTFE hydrophobic membranes.
[So] Source:J Environ Sci (China);45:28-39, 2016 Jul.
[Is] ISSN:1001-0742
[Cp] País de publicação:Netherlands
[La] Idioma:eng
[Ab] Resumo:Four common types of additives for polymer membrane preparation including organic macromolecule and micromolecule additives, inorganic salts and acids, and the strong non-solvent H2O were used to prepare poly (vinylidene fluoride-co-chlorotrifluoroethylene) (PVDF-CTFE) hydrophobic flat-sheet membranes. Membrane properties including morphology, porosity, hydrophobicity, pore size and pore distribution were investigated, and the permeability was evaluated via direct contact membrane distillation (DCMD) of 3.5g/L NaCl solution in a DCMD configuration. Both inorganic and organic micromolecule additives were found to slightly influence membrane hydrophobicity. Polyethylene glycol (PEG), organic acids, LiCl, MgCl2, and LiCl/H2O mixtures were proved to be effective additives to PVDF-CTFE membranes due to their pore-controlling effects and the capacity to improve the properties and performance of the resultant membranes. The occurrence of a pre-gelation process showed that when organic and inorganic micromolecules were added to PVDF-CTFE solution, the resultant membranes presented a high interconnectivity structure. The membrane prepared with dibutyl phthalate (DBP) showed a nonporous surface and symmetrical cross-section. When H2O and LiCl/H2O mixtures were also used as additives, they were beneficial for solid-liquid demixing, especially when LiCl/H2O mixed additives were used. The membrane prepared with 5% LiCl+2% H2O achieved a flux of 24.53kg/(m(2)·hr) with 99.98% salt rejection. This study is expected to offer a reference not only for PVDF-CTFE membrane preparation but also for other polymer membranes.
[Mh] Termos MeSH primário: Clorofluorcarbonetos/química
Membranas Artificiais
Polivinil/química
[Mh] Termos MeSH secundário: Destilação
Interações Hidrofóbicas e Hidrofílicas
Modelos Químicos
Porosidade
[Pt] Tipo de publicação:JOURNAL ARTICLE
[Nm] Nome de substância:
0 (Chlorofluorocarbons); 0 (Membranes, Artificial); 0 (Polyvinyls); 24937-79-9 (polyvinylidene fluoride); AF215GW34G (chlorotrifluoroethylene)
[Em] Mês de entrada:1701
[Cu] Atualização por classe:170127
[Lr] Data última revisão:
170127
[Sb] Subgrupo de revista:IM
[Da] Data de entrada para processamento:160704
[St] Status:MEDLINE


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[PMID]:27365432
[Au] Autor:Hand E
[Ti] Título:ATMOSPHERIC SCIENCE. CFC bans pay off as Antarctic ozone layer starts to mend.
[So] Source:Science;353(6294):16-7, 2016 Jul 01.
[Is] ISSN:1095-9203
[Cp] País de publicação:United States
[La] Idioma:eng
[Mh] Termos MeSH primário: Clorofluorcarbonetos/química
Perda de Ozônio/tendências
Ozônio Estratosférico/análise
[Mh] Termos MeSH secundário: Regiões Antárticas
Seres Humanos
[Pt] Tipo de publicação:NEWS
[Nm] Nome de substância:
0 (Chlorofluorocarbons); 0 (Stratospheric Ozone)
[Em] Mês de entrada:1608
[Cu] Atualização por classe:160701
[Lr] Data última revisão:
160701
[Sb] Subgrupo de revista:IM
[Da] Data de entrada para processamento:160702
[St] Status:MEDLINE
[do] DOI:10.1126/science.353.6294.16


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[PMID]:27365314
[Au] Autor:Solomon S; Ivy DJ; Kinnison D; Mills MJ; Neely RR; Schmidt A
[Ad] Endereço:Department of Earth, Atmospheric, and Planetary Sciences, Massachusetts Institute of Technology, Cambridge, MA 02139, USA.
[Ti] Título:Emergence of healing in the Antarctic ozone layer.
[So] Source:Science;353(6296):269-74, 2016 Jul 15.
[Is] ISSN:1095-9203
[Cp] País de publicação:United States
[La] Idioma:eng
[Ab] Resumo:Industrial chlorofluorocarbons that cause ozone depletion have been phased out under the Montreal Protocol. A chemically driven increase in polar ozone (or "healing") is expected in response to this historic agreement. Observations and model calculations together indicate that healing of the Antarctic ozone layer has now begun to occur during the month of September. Fingerprints of September healing since 2000 include (i) increases in ozone column amounts, (ii) changes in the vertical profile of ozone concentration, and (iii) decreases in the areal extent of the ozone hole. Along with chemistry, dynamical and temperature changes have contributed to the healing but could represent feedbacks to chemistry. Volcanic eruptions have episodically interfered with healing, particularly during 2015, when a record October ozone hole occurred after the Calbuco eruption.
[Mh] Termos MeSH primário: Clorofluorcarbonetos/química
Perda de Ozônio
Erupções Vulcânicas
[Mh] Termos MeSH secundário: Regiões Antárticas
Modelos Teóricos
Estações do Ano
[Pt] Tipo de publicação:JOURNAL ARTICLE; RESEARCH SUPPORT, NON-U.S. GOV'T; RESEARCH SUPPORT, U.S. GOV'T, NON-P.H.S.
[Nm] Nome de substância:
0 (Chlorofluorocarbons)
[Em] Mês de entrada:1610
[Cu] Atualização por classe:161230
[Lr] Data última revisão:
161230
[Sb] Subgrupo de revista:IM
[Da] Data de entrada para processamento:160702
[St] Status:MEDLINE
[do] DOI:10.1126/science.aae0061


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[PMID]:26945929
[Au] Autor:MacGregor TR; ZuWallack R; Rubano V; Castles MA; Dewberry H; Ghafouri M; Wood CC
[Ad] Endereço:Boehringer Ingelheim Pharmaceuticals Inc, Ridgefield, Connecticut, USA.
[Ti] Título:Efficiency of Ipratropium Bromide and Albuterol Deposition in the Lung Delivered via a Soft Mist Inhaler or Chlorofluorocarbon Metered-Dose Inhaler.
[So] Source:Clin Transl Sci;9(2):105-13, 2016 Apr.
[Is] ISSN:1752-8062
[Cp] País de publicação:United States
[La] Idioma:eng
[Ab] Resumo:The propellant-free Combivent Respimat Soft Mist Inhaler (CVT-R) was developed to replace the chlorofluorocarbon-propelled Combivent metered-dose inhaler (CVT-MDI). This steady-state pharmacokinetic (PK) substudy evaluated drug lung-delivery efficiency, using data from two phase III safety and efficacy trials. PK parameters were obtained from well-controlled population PK analyses. Area under the plasma concentration-time curve (AUC), maximum observed plasma concentration (C(max)), and minimum observed plasma concentration (C(min)) showed systemic exposure to ipratropium bromide and albuterol delivered via the CVT-R was proportional to ex-mouthpiece delivered dose. Although the labeled dose of ipratropium bromide in the CVT-R was half that in the CVT-MDI, the systemic exposure was comparable. No PK interaction for the ipratropium bromide and albuterol Respimat drug components was demonstrated. Ipratropium bromide alone resulted in similar exposure to the combination of ipratropium bromide and albuterol. These results show that CVT-R delivers drug more efficiently to the lung than CVT-MDI.
[Mh] Termos MeSH primário: Albuterol/administração & dosagem
Clorofluorcarbonetos/administração & dosagem
Ipratrópio/administração & dosagem
Pulmão/efeitos dos fármacos
Inaladores Dosimetrados
[Mh] Termos MeSH secundário: Administração por Inalação
Albuterol/sangue
Albuterol/farmacocinética
Intervalos de Confiança
Feminino
Seres Humanos
Ipratrópio/sangue
Ipratrópio/farmacocinética
Masculino
Resultado do Tratamento
[Pt] Tipo de publicação:CLINICAL TRIAL, PHASE III; JOURNAL ARTICLE; MULTICENTER STUDY; RANDOMIZED CONTROLLED TRIAL; RESEARCH SUPPORT, NON-U.S. GOV'T
[Nm] Nome de substância:
0 (Chlorofluorocarbons); GR88G0I6UL (Ipratropium); QF8SVZ843E (Albuterol)
[Em] Mês de entrada:1612
[Cu] Atualização por classe:170525
[Lr] Data última revisão:
170525
[Sb] Subgrupo de revista:IM
[Da] Data de entrada para processamento:160307
[St] Status:MEDLINE
[do] DOI:10.1111/cts.12387


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[PMID]:26707981
[Au] Autor:Yuan D; Yang GP; He Z
[Ad] Endereço:Key Laboratory of Marine Chemistry Theory and Technology, Ocean University of China, Ministry of Education/Qingdao Collaborative Innovation Center of Marine Science and Technology, Qingdao 266100, China; Institute of Marine Chemistry, Ocean University of China, Qingdao 266100, China.
[Ti] Título:Spatio-temporal distributions of chlorofluorocarbons and methyl iodide in the Changjiang (Yangtze River) estuary and its adjacent marine area.
[So] Source:Mar Pollut Bull;103(1-2):247-259, 2016 Feb 15.
[Is] ISSN:1879-3363
[Cp] País de publicação:England
[La] Idioma:eng
[Ab] Resumo:Temporal and spatial distribution patterns of volatile halogenated organic compounds (VHOCs), such as dichlorodifluoromethane (CFC-12), trichlorofluoromethane (CFC-11), trichlorotrifluoroethane (CFC-113), and methyl iodide (CH3I), in the Changjiang (Yangtze River) estuary and its adjacent marine area were measured during two cruises from 21 February to 10 March 2014 and from 10 to 21 July 2014. VHOC concentrations showed seasonal variation with higher values during winter. VHOC distributions evidently decreased along the freshwater plume from the river mouth to the open sea and from inshore to offshore regions. VHOC distributions were obviously influenced by the Changjiang runoff, anthropogenic inputs, and biological release of phytoplankton. The study area was a net sink for CFC-12 and CFC-11, but a net source for atmospheric CH3I during the study periods.
[Mh] Termos MeSH primário: Clorofluorcarbonetos/análise
Hidrocarbonetos Iodados/análise
Rios/química
Poluentes Químicos da Água/análise
[Mh] Termos MeSH secundário: Estuários
Oceanos e Mares
Fitoplâncton
Estações do Ano
[Pt] Tipo de publicação:JOURNAL ARTICLE; RESEARCH SUPPORT, NON-U.S. GOV'T
[Nm] Nome de substância:
0 (Chlorofluorocarbons); 0 (Hydrocarbons, Iodinated); 0 (Water Pollutants, Chemical); DAT010ZJSR (methyl iodide)
[Em] Mês de entrada:1611
[Cu] Atualização por classe:170821
[Lr] Data última revisão:
170821
[Sb] Subgrupo de revista:IM
[Da] Data de entrada para processamento:151229
[St] Status:MEDLINE


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[PMID]:26702867
[Au] Autor:Recio-Pinto E; Montoya-Gacharna JV; Xu F; Blanck TJ
[Ad] Endereço:From the Department of Anesthesiology, NYU Langone Medical Center, New York, New York.
[Ti] Título:Isoflurane, but Not the Nonimmobilizers F6 and F8, Inhibits Rat Spinal Cord Motor Neuron CaV1 Calcium Currents.
[So] Source:Anesth Analg;122(3):730-7, 2016 Mar.
[Is] ISSN:1526-7598
[Cp] País de publicação:United States
[La] Idioma:eng
[Ab] Resumo:BACKGROUND: Volatile anesthetics decrease Ca²âº entry through voltage-dependent Ca²âº channels. Ca influences neurotransmitter release and neuronal excitability. Because volatile anesthetics act specifically on the spinal cord to produce immobility, we examined the effect of isoflurane and the nonimmobilizers F6 (1, 2-dichlorohexafluorocyclobutane) and F8 (2, 3-dichlorooctafluorobutane) on CaV1 and CaV2 Ca²âº channels in spinal cord motor neurons and dorsal root ganglion neurons. METHODS: Using patch clamping, we compared the effects of isoflurane with those of F6 and F8 on CaV1 and CaV2 channels in isolated, cultured adult rat spinal cord motor neurons and on CaV1 and CaV2 channels in adult rat dorsal root ganglion sensory neurons. RESULTS: In spinal cord motor neurons, isoflurane, but not F6 or F8, inhibited currents through CaV1 channels. Isoflurane and at least one of the nonimmobilizers inhibited currents through CaV1 and CaV2 channels in dorsal root ganglion neurons and CaV2 in spinal cord motor neurons. CONCLUSIONS: The findings that isoflurane, but not nonimmobilizers, inhibited CaV1 Ca²âº channels in spinal cord motor neurons are consistent with the notion that spinal cord motor neurons might mediate isoflurane-induced immobility. Additional studies are required to examine whether inhibition of CaV1 calcium currents in spinal cord motor neurons is sufficient or whether actions on other channels/proteins contribute to isoflurane-induced immobility.
[Mh] Termos MeSH primário: Anestésicos Inalatórios/farmacologia
Bloqueadores dos Canais de Cálcio/farmacologia
Canais de Cálcio Tipo L/efeitos dos fármacos
Clorofluorcarbonetos/farmacologia
Ciclobutanos/farmacologia
Isoflurano/farmacologia
Neurônios Motores/efeitos dos fármacos
Medula Espinal/efeitos dos fármacos
[Mh] Termos MeSH secundário: Animais
Gânglios Espinais/citologia
Gânglios Espinais/efeitos dos fármacos
Técnicas de Patch-Clamp
Cultura Primária de Células
Ratos
Ratos Sprague-Dawley
Células Receptoras Sensoriais/efeitos dos fármacos
Medula Espinal/citologia
[Pt] Tipo de publicação:JOURNAL ARTICLE; RESEARCH SUPPORT, N.I.H., EXTRAMURAL; RESEARCH SUPPORT, NON-U.S. GOV'T
[Nm] Nome de substância:
0 (Anesthetics, Inhalation); 0 (Calcium Channel Blockers); 0 (Calcium Channels, L-Type); 0 (Chlorofluorocarbons); 0 (Cyclobutanes); 355-20-4 (2,3-dichlorooctafluorobutane); 356-18-3 (1,2-dichloro-1,2,3,3,4,4-hexafluorocyclobutane); CYS9AKD70P (Isoflurane)
[Em] Mês de entrada:1607
[Cu] Atualização por classe:170301
[Lr] Data última revisão:
170301
[Sb] Subgrupo de revista:AIM; IM
[Da] Data de entrada para processamento:151226
[St] Status:MEDLINE
[do] DOI:10.1213/ANE.0000000000001111



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