Base de dados : MEDLINE
Pesquisa : E05.301.250 [Categoria DeCS]
Referências encontradas : 2503 [refinar]
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  1 / 2503 MEDLINE  
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[PMID]:29446290
[Au] Autor:Shayakhmetov SV; Lisetskaya LG; Meshchakova NM; Merinov AV
[Ti] Título:[Hygienic assessment of toxic dust factor at the aluminium smelter in Eastern Siberia].
[So] Source:Gig Sanit;95(12):1155-60, 2016.
[Is] ISSN:0016-9900
[Cp] País de publicação:Russia (Federation)
[La] Idioma:rus
[Ab] Resumo:There is presented the assessment of priority toxic matters in the air of working zone for basic occupations of aluminum smelting by electrolysis. There are presented results of different production technologies. There are presented the results of the physical-chemical analysis of the morphology and composition of produced toxic-dust complexes.
[Mh] Termos MeSH primário: Poluentes Ocupacionais do Ar
Alumínio
Indústria Química
Poeira/análise
[Mh] Termos MeSH secundário: Poluentes Ocupacionais do Ar/análise
Poluentes Ocupacionais do Ar/toxicidade
Alumínio/análise
Alumínio/química
Indústria Química/métodos
Indústria Química/normas
Misturas Complexas/análise
Misturas Complexas/toxicidade
Eletrólise/métodos
Seres Humanos
Ciência dos Materiais/métodos
Exposição Ocupacional/efeitos adversos
Exposição Ocupacional/análise
Exposição Ocupacional/prevenção & controle
Saúde do Trabalhador
Sibéria/epidemiologia
[Pt] Tipo de publicação:JOURNAL ARTICLE
[Nm] Nome de substância:
0 (Air Pollutants, Occupational); 0 (Complex Mixtures); 0 (Dust); CPD4NFA903 (Aluminum)
[Em] Mês de entrada:1803
[Cu] Atualização por classe:180309
[Lr] Data última revisão:
180309
[Sb] Subgrupo de revista:IM
[Da] Data de entrada para processamento:180216
[St] Status:MEDLINE


  2 / 2503 MEDLINE  
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[PMID]:29247929
[Au] Autor:Lee SL; Ho LN; Ong SA; Wong YS; Voon CH; Khalik WF; Yusoff NA; Nordin N
[Ad] Endereço:School of Materials Engineering, Universiti Malaysia Perlis, 02600 Arau, Perlis, Malaysia.
[Ti] Título:Role of dissolved oxygen on the degradation mechanism of Reactive Green 19 and electricity generation in photocatalytic fuel cell.
[So] Source:Chemosphere;194:675-681, 2018 Mar.
[Is] ISSN:1879-1298
[Cp] País de publicação:England
[La] Idioma:eng
[Ab] Resumo:In this study, a membraneless photocatalytic fuel cell with zinc oxide loaded carbon photoanode and platinum loaded carbon cathode was constructed to investigate the impact of dissolved oxygen on the mechanism of dye degradation and electricity generation of photocatalytic fuel cell. The photocatalytic fuel cell with high and low aeration rate, no aeration and nitrogen purged were investigated, respectively. The degradation rate of diazo dye Reactive Green 19 and the electricity generation was enhanced in photocatalytic fuel cell with higher dissolved oxygen concentration. However, the photocatalytic fuel cell was still able to perform 37% of decolorization in a slow rate (k = 0.033 h ) under extremely low dissolved oxygen concentration (approximately 0.2 mg L ) when nitrogen gas was introduced into the fuel cell throughout the 8 h. However, the change of the UV-Vis spectrum indicates that the intermediates of the dye could not be mineralized under insufficient dissolved oxygen level. In the aspect of electricity generation, the maximum short circuit current (0.0041 mA cm ) and power density (0.00028 mW cm ) of the air purged photocatalytic fuel cell was obviously higher than that with nitrogen purging (0.0015 mA cm and 0.00008 mW cm ).
[Mh] Termos MeSH primário: Compostos Azo/química
Eletricidade
Eletrólise/métodos
Oxigênio/química
[Mh] Termos MeSH secundário: Carbono
Catálise
Eletrodos
Processos Fotoquímicos
Platina
Óxido de Zinco
[Pt] Tipo de publicação:JOURNAL ARTICLE
[Nm] Nome de substância:
0 (Azo Compounds); 0 (reactive green 19); 49DFR088MY (Platinum); 7440-44-0 (Carbon); S88TT14065 (Oxygen); SOI2LOH54Z (Zinc Oxide)
[Em] Mês de entrada:1802
[Cu] Atualização por classe:180228
[Lr] Data última revisão:
180228
[Sb] Subgrupo de revista:IM
[Da] Data de entrada para processamento:171217
[St] Status:MEDLINE


  3 / 2503 MEDLINE  
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[PMID]:29024885
[Au] Autor:Jager D; Kupka D; Vaclavikova M; Ivanicova L; Gallios G
[Ad] Endereço:Institute of Geotechnics, Slovak Academy of Sciences, Watsonova 45, 040 01, Kosice, Slovakia.
[Ti] Título:Degradation of Reactive Black 5 by electrochemical oxidation.
[So] Source:Chemosphere;190:405-416, 2018 Jan.
[Is] ISSN:1879-1298
[Cp] País de publicação:England
[La] Idioma:eng
[Ab] Resumo:Degradation of commercial grade Reactive Black 5 (RB5) azo dye by chemical and electrochemical treatment was examined using a dimensionally stable anode and stainless steel cathodes as electrode materials, with NaCl as supporting electrolyte. The electrochemical treatment was compared to the chemical treatment with hypochlorite generated by electrolysis. The compounds present in the commercial grade RB5 azo dye and the products of its electrochemical degradation were separated using ion-pairing high performance liquid chromatography on reversed phase. The separated species were detected by diode array detector and electrospray ionization mass spectrometry. A suitable ion-pairing reversed phase HPLC-MS method with electrospray ionization for the separation and identification of the components was developed. The accurate mass of the parent and fragment ions were used in the determination of the empirical formulas of the components using the first-order mass spectra. Structural formulas of degradation products were proposed using these information and principles of organic chemistry and electrochemistry.
[Mh] Termos MeSH primário: Eletrólise/métodos
Naftalenossulfonatos/química
[Mh] Termos MeSH secundário: Compostos Azo/química
Cromatografia Líquida de Alta Pressão/métodos
Corantes/química
Estrutura Molecular
Peso Molecular
Oxirredução
Espectrometria de Massas por Ionização por Electrospray/métodos
Purificação da Água/métodos
[Pt] Tipo de publicação:JOURNAL ARTICLE
[Nm] Nome de substância:
0 (Azo Compounds); 0 (Coloring Agents); 0 (Naphthalenesulfonates); O0HDY58362 (Remazol black B)
[Em] Mês de entrada:1802
[Cu] Atualização por classe:180228
[Lr] Data última revisão:
180228
[Sb] Subgrupo de revista:IM
[Da] Data de entrada para processamento:171013
[St] Status:MEDLINE


  4 / 2503 MEDLINE  
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[PMID]:29406115
[Au] Autor:Jin Y; Yue Q; Yang K; Wu S; Li S; Gao B; Gao Y
[Ad] Endereço:Shandong University, Jinan 250100, China.
[Ti] Título:Pre-treatment of pyridine wastewater by new cathodic-anodic-electrolysis packing.
[So] Source:J Environ Sci (China);63:43-49, 2018 Jan.
[Is] ISSN:1001-0742
[Cp] País de publicação:Netherlands
[La] Idioma:eng
[Ab] Resumo:A novel cathodic-anodic-electrolysis packing (CAEP) used in the treatment of pyridine wastewater was researched, which mainly consisted of 4,4'-diamino-2,2'-disulfonic acid (DSD acid) industrial iron sludge. The physical properties and morphology of the packing were studied. The CAEP was used in a column reactor during the pretreatment of pyridine wastewater. The influence of pH, hydraulic retention time (HRT), the air-liquid ratio (A/L) and the initial concentration of pyridine were investigated by measuring the removal of total organic carbon (TOC) and pyridine. The characterization results showed that the bulk density, grain density, water absorption percentage and specific surface area were 921kg/m , 1086kg/m , 25% and 29.89m /g, respectively; the removal of TOC and pyridine could reach 50% and 58% at the optimal experimental conditions (pH=3, HRT=8hr, A/L=2). Notably, the surface of the packing was renewed constantly during the running of the filter, and the handling capacity was stable after running for three months.
[Mh] Termos MeSH primário: Eletrólise
Piridinas/química
Eliminação de Resíduos Líquidos/métodos
Águas Residuais/química
Poluentes Químicos da Água/química
[Mh] Termos MeSH secundário: Técnicas Eletroquímicas
Eletrodos
Poluentes Químicos da Água/análise
[Pt] Tipo de publicação:JOURNAL ARTICLE
[Nm] Nome de substância:
0 (Pyridines); 0 (Waste Water); 0 (Water Pollutants, Chemical)
[Em] Mês de entrada:1802
[Cu] Atualização por classe:180216
[Lr] Data última revisão:
180216
[Sb] Subgrupo de revista:IM
[Da] Data de entrada para processamento:180207
[St] Status:MEDLINE


  5 / 2503 MEDLINE  
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[PMID]:29324786
[Au] Autor:Reipa V; Atha DH; Coskun SH; Sims CM; Nelson BC
[Ad] Endereço:Materials Measurement Laboratory, Biosystems and Biomaterials Division, National Institute of Standards and Technology, Gaithersburg, Maryland, United States of America.
[Ti] Título:Controlled potential electro-oxidation of genomic DNA.
[So] Source:PLoS One;13(1):e0190907, 2018.
[Is] ISSN:1932-6203
[Cp] País de publicação:United States
[La] Idioma:eng
[Ab] Resumo:Exposure of mammalian cells to oxidative stress can result in DNA damage that adversely affects many cell processes. Lack of dependable DNA damage reference materials and standardized measurement methods, despite many case-control studies hampers the wider recognition of the link between oxidatively degraded DNA and disease risk. We used bulk electrolysis in an electrochemical system and gas chromatographic mass spectrometric analysis (GC/MS/MS) to control and measure, respectively, the effect of electrochemically produced reactive oxygen species on calf thymus DNA (ct-DNA). DNA was electro-oxidized for 1 h at four fixed oxidizing potentials (E = 0.5 V, 1.0 V, 1.5 V and 2 V (vs Ag/AgCl)) using a high surface area boron-doped diamond (BDD) working electrode (WE) and the resulting DNA damage in the form of oxidatively-modified DNA lesions was measured using GC/MS/MS. We have shown that there are two distinct base lesion formation modes in the explored electrode potential range, corresponding to 0.5 V < E < 1.5 V and E > 1.5 V. Amounts of all four purine lesions were close to a negative control levels up to E = 1.5 V with evidence suggesting higher levels at the lowest potential of this range (E = 0.5 V). A rapid increase in all base lesion yields was measured when ct-DNA was exposed at E = 2 V, the potential at which hydroxyl radicals were efficiently produced by the BDD electrode. The present results demonstrate that controlled potential preparative electrooxidation of double-stranded DNA can be used to purposely increase the levels of oxidatively modified DNA lesions in discrete samples. It is envisioned that these DNA samples may potentially serve as analytical control or quality assurance reference materials for the determination of oxidatively induced DNA damage.
[Mh] Termos MeSH primário: DNA/química
[Mh] Termos MeSH secundário: Animais
Boro
Bovinos
Diamante
Eletrodos
Eletrólise
Cromatografia Gasosa-Espectrometria de Massas
Radical Hidroxila/química
Oxirredução
Purinas/química
Pirimidinas/química
[Pt] Tipo de publicação:JOURNAL ARTICLE; RESEARCH SUPPORT, NON-U.S. GOV'T
[Nm] Nome de substância:
0 (Purines); 0 (Pyrimidines); 3352-57-6 (Hydroxyl Radical); 7782-40-3 (Diamond); 9007-49-2 (DNA); 91080-16-9 (calf thymus DNA); N9E3X5056Q (Boron)
[Em] Mês de entrada:1802
[Cu] Atualização por classe:180206
[Lr] Data última revisão:
180206
[Sb] Subgrupo de revista:IM
[Da] Data de entrada para processamento:180112
[St] Status:MEDLINE
[do] DOI:10.1371/journal.pone.0190907


  6 / 2503 MEDLINE  
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[PMID]:28873606
[Au] Autor:Qi H; Huang Q; Hung YC
[Ad] Endereço:Department of Food Science and Technology, University of Georgia, 1109 Experiment Street, Griffin, GA 30223, USA. Electronic address: qihang@uga.edu.
[Ti] Título:Effectiveness of electrolyzed oxidizing water treatment in removing pesticide residues and its effect on produce quality.
[So] Source:Food Chem;239:561-568, 2018 Jan 15.
[Is] ISSN:0308-8146
[Cp] País de publicação:England
[La] Idioma:eng
[Ab] Resumo:This study evaluated the effects of electrolyzed oxidizing (EO) water treatment on the removal of pesticide residues (diazinon, cyprodinil and phosmet) from spinach, snap beans and grapes, and the effect on produce quality. High available chlorine content (ACC) and long treatment time of EO water resulted in high pesticide removals. Up to 59.2, 66.5 and 37.1% of diazinon; 43.8, 50.0 and 31.5% of cyprodinil; 85.7, 73.0 and 49.4% of phosmet; were removed from spinach, snap beans and grapes, respectively, after 15min EO water treatment at 120mg/l ACC. EO water was also more effective than electrolyzed reduced water, bleach, VegWash and DI water on pesticide removal. In addition, no significant colour or texture deterioration were found on produce samples treated with EO water. It was concluded, EO water can be very effective in pesticide residue removal from fresh produce without affecting the produce quality.
[Mh] Termos MeSH primário: Resíduos de Praguicidas/análise
[Mh] Termos MeSH secundário: Cloro
Contagem de Colônia Microbiana
Eletrólise
Concentração de Íons de Hidrogênio
Oxirredução
Água
Purificação da Água
[Pt] Tipo de publicação:JOURNAL ARTICLE
[Nm] Nome de substância:
0 (Pesticide Residues); 059QF0KO0R (Water); 4R7X1O2820 (Chlorine)
[Em] Mês de entrada:1711
[Cu] Atualização por classe:171128
[Lr] Data última revisão:
171128
[Sb] Subgrupo de revista:IM
[Da] Data de entrada para processamento:170907
[St] Status:MEDLINE


  7 / 2503 MEDLINE  
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[PMID]:28847080
[Au] Autor:Ye B; Luo H; Lu Y; Liu G; Zhang R; Li X
[Ad] Endereço:Guangdong Provincial Key Laboratory of Environmental Pollution Control and Remediation Technology, School of Environmental Science and Engineering, Sun Yat-sen University, Guangzhou 510275, China.
[Ti] Título:Improved performance of the microbial electrolysis desalination and chemical-production cell with enlarged anode and high applied voltages.
[So] Source:Bioresour Technol;244(Pt 1):913-919, 2017 Nov.
[Is] ISSN:1873-2976
[Cp] País de publicação:England
[La] Idioma:eng
[Ab] Resumo:The aim of this study was to improve performance of the microbial electrolysis desalination and chemical-production cell (MEDCC) using enlarged anode and high applied voltages. MEDCCs with anode lengths of 9 and 48cm (i.e., the 9cm-anode MEDCC and 48cm-anode MEDCC, respectively) were tested under different voltages (1.2-3.0V). Our results demonstrated for the first time that the MEDCC could maintain high performance even under the applied voltage higher than that for water dissociation (i.e., 1.8V). Under the applied voltage of 2.5V, the maximum current density in the 48cm-anode MEDCC reached 32.8±2.6A/m , which is one of the highest current densities reported so far in the bioelectrochemical system (BES). The relative abundance of Geobacter was changed along the anode length. Our results show the great potential of the BES with enlarged anode and high applied voltages.
[Mh] Termos MeSH primário: Fontes de Energia Bioelétrica
[Mh] Termos MeSH secundário: Bactérias
Eletrodos
Eletrólise
Geobacter
[Pt] Tipo de publicação:JOURNAL ARTICLE
[Em] Mês de entrada:1710
[Cu] Atualização por classe:171023
[Lr] Data última revisão:
171023
[Sb] Subgrupo de revista:IM
[Da] Data de entrada para processamento:170830
[St] Status:MEDLINE


  8 / 2503 MEDLINE  
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[PMID]:28759448
[Au] Autor:Gao J; Yan J; Liu Y; Zhang J; Guo Z
[Ad] Endereço:Research Center of Shanxi Province for High Gravity Chemical Engineering and Technology, North University of China, Taiyuan 030051, Shanxi Province, China E-mail: zbgaojing@163.com.
[Ti] Título:A novel electro-catalytic degradation method of phenol wastewater with Ti/IrO -Ta O anodes in high-gravity fields.
[So] Source:Water Sci Technol;76(3-4):662-670, 2017 Jul.
[Is] ISSN:0273-1223
[Cp] País de publicação:England
[La] Idioma:eng
[Ab] Resumo:In the electro-catalytic degradation process of phenol wastewater, bubbles and mass transfer limitation will result in the decrease in wastewater degradation efficiency, a long electrolysis time and a high energy consumption. Self-made Ti/IrO -Ta O anodes and a high-gravity electro-catalytic reactor were used to improve them. The Ti/IrO -Ta O anode was prepared with a thermal decomposition method and characterized by scanning electron microscopy (SEM). Under optimum conditions, the removal efficiencies of phenol, total organic carbon (TOC) and chemical oxygen demand (COD) respectively reached 94.77%, 50.96% and 41.2% after 2 h electrolysis in the high-gravity field, which were respectively 10.93%, 16.72% and 24.84% higher than those in the normal gravity field. For about the same removal efficiencies, the electrolysis time and energy consumed in the high-gravity field were 33.3% and 15.4% lower than those consumed in the normal gravity field, respectively. The degradation pathway of phenol detected by high performance liquid chromatography (HPLC) was unchanged in the high-gravity field, but the degradation rate of phenol increased. The Ti/IrO -Ta O anode provided good stability because the removal efficiencies of phenol and TOC decreased slightly and the surface morphology of the coating was almost unchanged when it had been used in electrolysis for 11 months, about 1,200 h, in the high-gravity field. Results indicated that the phenol wastewater degradation efficiency was improved, the time was shortened, and the energy consumption was reduced in the high-gravity field.
[Mh] Termos MeSH primário: Eletroquímica/métodos
Óxidos/química
Fenol/química
Tantálio/química
Titânio/química
Águas Residuais
Poluentes Químicos da Água/química
[Mh] Termos MeSH secundário: Catálise
Eletroquímica/instrumentação
Eletrodos
Eletrólise
Irídio/química
Fenóis
[Pt] Tipo de publicação:JOURNAL ARTICLE
[Nm] Nome de substância:
0 (Oxides); 0 (Phenols); 0 (Waste Water); 0 (Water Pollutants, Chemical); 12030-49-8 (iridium oxide); 339NCG44TV (Phenol); 44448S9773 (Iridium); 6424HBN274 (Tantalum); D1JT611TNE (Titanium); OEZ64Z53M4 (tantalum oxide)
[Em] Mês de entrada:1710
[Cu] Atualização por classe:171116
[Lr] Data última revisão:
171116
[Sb] Subgrupo de revista:IM
[Da] Data de entrada para processamento:170801
[St] Status:MEDLINE
[do] DOI:10.2166/wst.2017.262


  9 / 2503 MEDLINE  
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[PMID]:28719849
[Au] Autor:Pozo G; Lu Y; Pongy S; Keller J; Ledezma P; Freguia S
[Ad] Endereço:Advanced Water Management Centre, the University of Queensland, St Lucia, QLD 4072, Australia. Electronic address: g.pozozamora@awmc.uq.edu.au.
[Ti] Título:Selective cathodic microbial biofilm retention allows a high current-to-sulfide efficiency in sulfate-reducing microbial electrolysis cells.
[So] Source:Bioelectrochemistry;118:62-69, 2017 Dec.
[Is] ISSN:1878-562X
[Cp] País de publicação:Netherlands
[La] Idioma:eng
[Ab] Resumo:Selective microbial retention is of paramount importance for the long-term performance of cathodic sulfate reduction in microbial electrolysis cells (MECs) due to the slow growth rate of autotrophic sulfate-reducing bacteria. In this work, we investigate the biofilm retention and current-to-sulfide conversion efficiency using carbon granules (CG) or multi-wall carbon nanotubes deposited on reticulated vitreous carbon (MWCNT-RVC) as electrode materials. For ~2months, the MECs were operated at sulfate loading rates of 21 to 309gSO -S/m /d. Although MWCNT-RVC achieved a current density of 57±11A/m , greater than the 32±9A/m observed using CG, both materials exhibited similar sulfate reduction rates (SRR), with MWCNT-RVC reaching 104±16gSO -S/m /d while 110±13gSO -S/m /d were achieved with CG. Pyrosequencing analysis of the 16S rRNA at the end of experimentation revealed a core community dominated by Desulfovibrio (28%), Methanobacterium (19%) and Desulfomicrobium (14%), on the MWCNT-RVC electrodes. While a similar Desulfovibrio relative abundance of 29% was found in CG-biofilms, Desulfomicrobium was found to be significantly less abundant (4%) and Methanobacterium practically absent (0.2%) on CG electrodes. Surprisingly, our results show that CG can achieve higher current-to-sulfide efficiencies at lower power consumption than the nano-modified three-dimensional MWCNT-RVC.
[Mh] Termos MeSH primário: Bactérias/metabolismo
Biofilmes
Condutividade Elétrica
Eletrólise/instrumentação
Sulfatos/metabolismo
Sulfetos/metabolismo
[Mh] Termos MeSH secundário: Eletrodos
Concentração de Íons de Hidrogênio
Nanotubos de Carbono/química
Sulfatos/química
Sulfetos/química
[Pt] Tipo de publicação:JOURNAL ARTICLE
[Nm] Nome de substância:
0 (Nanotubes, Carbon); 0 (Sulfates); 0 (Sulfides)
[Em] Mês de entrada:1709
[Cu] Atualização por classe:170927
[Lr] Data última revisão:
170927
[Sb] Subgrupo de revista:IM
[Da] Data de entrada para processamento:170719
[St] Status:MEDLINE


  10 / 2503 MEDLINE  
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[PMID]:28701652
[Au] Autor:Morimoto M; Urakawa M; Komai K
[Ad] Endereço:Department of Applied Biological Chemistry, School of Agriculture, Kindai University.
[Ti] Título:Electrochemical Synthesis of Dihydrobenzofurans and Evaluation of Their Insect Antifeedant Activities.
[So] Source:J Oleo Sci;66(8):857-862, 2017 Aug 01.
[Is] ISSN:1347-3352
[Cp] País de publicação:Japan
[La] Idioma:eng
[Ab] Resumo:Electrochemically synthesized dihydrobenzofurans were evaluated for their insect antifeedant activities against phytophagous insects. They were prepared through the coupling reactions of various alkenes with a phenoxy cation generated by oxidation near the cathode in the electrolytic reaction. The insect antifeedant activities of these synthetic dihydrobenzofurans were evaluated in the common cutworm (Spodoptera litura) and diamond back moth (Plutella xylostella) with the dual choice leaf disk bioassay method. The insect antifeedant activities of most of the acetophenone-type dihydrobenzofurans were strong, while those of derivatives with a t-butyl group were weaker. The biological activities in insect species differed with the structural features of the compounds.
[Mh] Termos MeSH primário: Benzofuranos/síntese química
Benzofuranos/farmacologia
Técnicas Eletroquímicas
Repelentes de Insetos
Mariposas/efeitos dos fármacos
Spodoptera/efeitos dos fármacos
[Mh] Termos MeSH secundário: Alcenos/química
Animais
Benzofuranos/química
Benzofuranos/classificação
Bioensaio/métodos
Eletrodos
Eletrólise
Oxirredução
Fenóis/química
Plantas/parasitologia
Relação Estrutura-Atividade
[Pt] Tipo de publicação:JOURNAL ARTICLE
[Nm] Nome de substância:
0 (Alkenes); 0 (Benzofurans); 0 (Insect Repellents); 0 (Phenols); 3229-70-7 (phenoxy radical)
[Em] Mês de entrada:1710
[Cu] Atualização por classe:171010
[Lr] Data última revisão:
171010
[Sb] Subgrupo de revista:IM
[Da] Data de entrada para processamento:170714
[St] Status:MEDLINE
[do] DOI:10.5650/jos.ess17022



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